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https://dspace.usfa.edu.ua/handle/123456789/1115| Title: | The properties and structure of N-chloro-N-methoxy-4-nitrobenzamide |
| Authors: | Shtamburg, Vasiliy G. Tsygankov, Alexander V. Shishkin, Oleg V. Zubatyuk, Roman I. Uspensky, Boris V. Shtamburg, Victor V. Victor V., Alexander V. Kostyanovsky, Remir G. |
| Keywords: | ACYLOXY-N-ALKOXYAMIDES GEMINAL SYSTEMS CRYSTAL-STRUCTURES ANOMERIC AMIDES NITROGEN ALKOXYUREAS DERIVATIVES UREAS |
| Issue Date: | 2012 |
| Publisher: | ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS |
| Citation: | The properties and structure of N-chloro-N-methoxy-4-nitrobenzamide / Vasiliy G. Shtamburg, Alexander V. Tsygankov, Oleg V. Shishkin and others // Mendeleev Commun. - 2012. - Volume: 22; Issue: 3. - P. 164-166. DOI: 10.1016/j.mencom.2012.05.019 |
| Abstract: | The XRD study of N-chloro-N-methoxy-4-nitrobenzamide revealed the high pyramidality degree of its amide nitrogen atom in O–N–Cl moiety. N-Chloro-N-methoxy-4-nitrobenzamide reacts with AcONa in MeCN selectively forming N-acetoxy-N-methoxy-4-nitrobenzamide, whereas its methanolysis in the presence of AcONa yields N,N'-bis(4-nitrobenzoyl)-N,N'-dimethoxyhydrazine. |
| URI: | http://dspace.sfa.org.ua:80/handle/123456789/1115 |
| Appears in Collections: | Наукові публікації |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Tsygankov_The_properties.pdf | 541.7 kB | Adobe PDF | View/Open |
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